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Epub 2017 Jul 7. Briefly, .the present invention is based on the discovery that a salt of meta-phthalic acid and a di-valent metal, for example the meta-phthalate of dievalent lead, ,copper or calcium, can .be transformed by treatment with applied heat or by exposing to ultra-violet radiation, into a mixture containing'meta-phthalic anhydride. The isophthalic acid market was rather tight during 2017 and part of 2018, but there have been new investments in 2019. At higher temperatures, there maybe other materials which distill with the metaphthalic anhydride. 6. It is an isomer of isophthalic acid and terephthalic acid. Creative Commons Attribution-Share-Alike License 3.0. This meta-analysis aims to evaluate the association between five different phthalate metabolites and endometriosis, based on current evidence. Systematic review and meta-analysis on the association between … Empirical Formula (Hill Notation) C 8 H 5 BrO 4. 5. Synonym: 1,2-Benzenedicarboxylic acid 1,2-bis(1-methylethyl) ester, NSC 15315, Phthalic acid diisopropyl ester Empirical Formula (Hill Notation): C 14 H 18 O 4 Molecular Weight: 250.29 Thank you for helping build the largest language community on the internet. It is relatively insoluble in cold water, moderately soluble in ethanol and carbon tetrachloride, and very soluble in benzene. phthalic acid (plural phthalic acids) (organic chemistry) Any of three isomeric aromatic organic benzenedicarboxylic acids, C 6 H 4 (COOH) 2; especially the ortho-isomer manufactured from naphthalene, used in the synthesis of dyes, perfumes and other compounds. It is an isomer of isophthalic acid and terephthalic acid. A new type of organic photoreaction, Improvements in the preparation of organophosphonic acids and their salts, Hydroxybenzeneboronic acids and anhydrides, STUDIES OP CERTAIN RED PIGMENTS FORMED FROM 2‐THIOBARBITURIC ACID a. and condensing the meta-phthalic acid anhydride. It is a white crystalline solid subliming at 345°C. You can also submit buying request for the Phthalic acid and specify your requirement on okchem.com, and we will help you find the quality Phthalic acid … MDL number MFCD00152019. In the preparation of meta-phthalic anhydride, a salt of meta-phthalic acid and a divalent metal, such as lead or copper metaphthalate, may first be subjected to radiant energy. Believing the resulting substance to be a naphthalene derivative, he named it "naphthalic acid". Substance identity Substance identity. Phthalate esters and childhood asthma: A systematic review and congener-specific meta-analysis Environ Pollut. okchem.com offers 37 Phthalic acid products from China and other countries around the world. Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner cupric meta-phthalate to a temperature of 500 degrees Fahrenheit to 850,degrees Fahrenheit to form meta-phthalic acid anhydride vapor. 9 met p thal c aci A u h 9 0 f thi fi l $33 1 i $9 p. 0- de a m t d f prepa n th a h dride c m -p iha a d. wh ch wi l b re erre to hereinafter as meta-phthalic anhydride. 1). 1‐octanol shows a good extractive selectivity for [1,1′‐biphenyl]‐2,2′‐dicarboxylic acid as compared with phthalic … However, many phthalate esters have been implicated as endocrine disruptors. t. The same product is obtained when thesalt is heated alone .to slightly higher optimum temperatures. '7. 8. Phthalamic acid definition is - a crystalline compound HOOCC6H4CONH2 formed by reaction of phthalic anhydride and ammonia; the half amide of phthalic acid. 55,823. It is an isomer of isophthalic acid and terephthalic acid. m-Phthalic acid. Epub 2019 Feb 8. Manufacture of meta-and para-phthalic acid esters Download PDF Info Publication number US3027400A. Sometimes the term "phthalic acids" is used to refer to this family of isomers, but in the singular, "phthalic acid", refers exclusively to the ortho- isomer. A. C. 8., vol. Orthophthalic acid definition, See under phthalic acid (def. [8] Manufacturing methods in the nineteenth century included oxidation of naphthalene tetrachloride with nitric acid, or, better, oxidation of the hydrocarbon with fuming sulfuric acid, using mercury or mercury(II) sulfate as a catalyst. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the … Having described my invention, what I claim as novel and desire to secure by Letters Patent is: l. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner salt of meta-phthalic acid and a divalent metal to'a'temperature of 500 degrees F. to approximately 850 degrees F. to form metaphthalic acid anhydride vapor and then condensing the meta-phthalic acid anhydride vapor. [6] After the Swiss chemist Jean Charles Galissard de Marignac determined its correct formula,[7] Laurent gave it its present name. REFERENCES CITED The following references are of record in the file of this patent: UNITED STATES PATENTS Number Name 7 Date 2,101,868 Mugdan et a1. Acide isophtalique. Typically phthalate esters are prepared from the widely available phthalic anhydride. Sign in to disable ALL ads. It was relatively insoluble in water, moderately soluble in ethanol and very soluble in benzene and exhibited the other properties set out hereinabove. Ea'ample I A sample of the meta.-phtha'l ate of di-valent ,leacl having a White color' was placed in an Example II A second sample of" the meta-phthalate of divalent lead was placed in an enclosed glass reaction vessel in an oxidizing atmosphere (air) and heated to a temperature of between degrees Fahrenheit and 850 degrees Fahrenheit for 10 minutes. Reduction of phthalic acid with sodium amalgam in the presence of water gives the 1,3-cyclohexadiene derivative.[9]. he h dr de 9 meta-rh lie acid has t b en lmpwn- The anhy r de 9 phth acid is c mma but meth ds by which ortho-phthalic acid anhydride is prepared have ot suc es nll rroduced th anhvd de of meta-phthalic acid. THE INNER ANHYDRIDE OF METAPHTHALIC ACID. Isophthalic acid definition, a colorless, crystalline, slightly water-soluble solid, C8H6O2, the meta isomer of phthalic acid: used chiefly in the manufacture of resins and plasticizers. Different isomers of phthalic acid are known by different names. Isophthalic acid’s second major use is as a component of high-quality alkyds and polyester resins for industrial coatings and unsaturated polyesters for fiberglass-reinforced plastics applications. It is a conjugate acid of a phthalate (1-) and a phthalate. m-Benzenedicarboxylic acid. (benzenedicarboxylic acid), C 6 H 4 (COOH) 2, any one of three dicarboxylic acids of the aromatic series: ortho-phthalic acid (or simply phthalic acid), meta-phthalic acid (or isophthalic acid), and para-phthalic acid (or terephthalic acid).All three are colorless crystals, with melting points of 200°C (with decomposition), 348°C, and 425°C (in a sealed tube), respectively. 31, pp. The following examples illustrate the .in- Vention more specifically, but the invention is not intended to be limited by the examples except as set out in the appended claims. Isophthalic acid is an organic compound with the formula C6H4(CO2H)2. 1319-1321 (1909). A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner meta-phthalate of di-valent lead to a temperature of 750 degrees Fahrenheit to about 850 degrees Fahrenheit for approximately 10 minutes to form meta-phthalic acid anhydride vapor, and condensing the meta-phthalic acid anhydride vapor. HSDB 2090. The material dissolves in aqueous alkali, such as ten percent sodium hydroxide solution; and when the sodium hydroxide solution is neutralized and rendered weakly acid with acetic acid, it gives an orange-pink color upon addition of ferric ion. [10], This article uses material from the Wikipedia article Environ Sci Pollut Res Int. The synthesis of 1-bromotriptycene, 1,3,5,7-Naphthalenetetracarboxylic acids and process for preparation thereof. Expired - Lifetime Application number US54823A Inventor Walton George In each of Examples II to IV, the salt of a di-valent metal and meta-phthalic acid is heated for a sufiicient time and to a temperature to cause formation of meta-phthalic acid anhydride vapor which is separated from residual material as a vapor and then condensed. The meta-ph-thalic anhydride may beseparated from residual oxides, meta-l salts, and other :byeproducts by heating to temperatures in the neighborhood of -500 to 850 degrees Fahrenheit, at which temperatures the-meta-ph-th-alie anhydride may be separated by sublimation. 4. Isophthalic acid, 99%. The monopotassium salt, potassium hydrogen phthalate is a standard acid in analytical chemistry. Phthalic acid is one of three isomers of benzenedicarboxylic acid, the others being isophthalic acid and terephthalic acid. A wide variety of Phthalic acid options are available to you. Slender transparent to white needles and feathers of meta-phthalic anhydride sublimed and condensed in cooler parts f the reaction vessel. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. Poly(ester-b-carbonate)s are successfully synthesized for the first time through the metal-free copolymerization of cyclohexene oxide (CHO), propylene oxide (PO), phthalic anhydride (PA), and CO2 in a one-pot/one-step protocol. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. There is a list of all PHTHALIC ACIDS, the name given to the three isomeric benzene-dicarboxylic acids, C6114(CO2H)2: (I) ortho, or phthalic acid; (2) meta, or isophthalic acid; (3) para, or terephthalic acid. AI3-16107. Kyselina isoftalova. Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. 685. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner calcium meta-phthalate to a temperature of approximately 800 degrees Fahrenheit to form meta-phthalic acid anhydride vapor, and condensing the meta-phthalic acid anhydride. It has a role as a human xenobiotic metabolite. The exposure of the divalent metal salts of meta-phthalic acid to radiant energy may be in the dry state or the vapor state; After irradiation of the salt, the product may be removed by heating the mixed reaction prod-.-, - not to temperatures between 500 degrees Fahrenheit and 850 degrees Fahrenheit, the optimum temperature being about 700 degrees Fahrenheit. "", which is released under the 5-Bromoisophthalic acid Synonym: 5-Bromo-1,3-benzenedicarbonic acid, 5-Bromo-1,3-benzenedicarboxylic acid, 5-Bromoisophthalic acid CAS Number 23351-91-9. iso-phthalic acid. BRN 1909332. meta-benzenedicarboxylic acid. See more. The anhydride may be separated from these other materials which may distill with it by reesublimation, extraction with a solvent such as benzene, or by other suitable separation methods. authors in Wikipedia, database,rohs,reach,compliancy,directory,listing,information,substance,material,restrictions,data sheet,specification, InChI=1S/C8H6O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)(H,11,12), InChI=1/C8H6O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)(H,11,12), Except where otherwise noted, data are given for materials in their, This website uses tracking mechanisms by using technically not necessary cookies in order to offer and constantly improve its services, and to provide individual offers. The reaction between indole and acetic anhydride, Process for the preparation of benzoic acid and benzoates, Bicyclic structures prohibiting the walden inversion. 3. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner salt of meta-phthalic acid and a divalent metal selected from the group consisting of lead, copper, and calcium to a temperature of 500 degrees F. to about 850 degrees F. to form meta-phthalic acid anhydride vapor and condensing the meta-phthalic acid anhydride vapor. A PROCESS FOR PREPARING THE INNER ANHYDRIDE OF META-PHTHALIC ACID WHICH COMPRISES HEATING THE INNER SALT OF META-PHTHALIC ACID AND A DIVALENT METAL TO A TEMPERATURE OF 500 DEGREES F. TO APPROXIMATELY 850 DEGREES F. TO FORM METAPHTHALIC ACID ANHYDRIDE VAPOR AND THEN CONDENSING THE META-PHTHALIC ACID ANHYDRIDE VAPOR. 1. PubChem Substance ID 329763040. meta-Phosphoric acid pieces for analysis (stabilized with sodium metaphosphate) EMSURE® - Find MSDS or SDS, a COA, data sheets and more information. 2019 Apr;26(10):9435-9442. doi: 10.1007/s11356-019-04373-1. V. Slender transparent to white needles and feathers of meta-phthalic anhydride sublimed and condensed in cooler parts of the reaction vessel. Example III Example IV A sample of anhydrous calcium meta-phthalate was placed in an enclosed glass reaction vessel in an oxidizing atmosphere (air) and heated to a temperature of approximately 800 degrees- Fahrenheit for minutes. Listen to the audio pronunciation of Meta-phthalic acid on pronouncekiwi. US3027400A US5631A US563160A US3027400A US 3027400 A US3027400 A US 3027400A US 5631 A US5631 A US 5631A US 563160 A US563160 A US 563160A US 3027400 A US3027400 A US 3027400A Authority US United States Prior art keywords alcohol trimellitic acid Phthalic acid is a benzenedicarboxylic acid cosisting of two carboxy groups at ortho positions. Meta-phthalic acid anhydride and method of making same, 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Preparation of carboxylic acids or their salts, halides or anhydrides, Preparation of carboxylic acid anhydrides, Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. Of meta-and para-phthalic acid esters Download PDF Info Publication number US3027400A of three isomers of benzenedicarboxylic acid, with C6H4! Presence of water gives the 1,3-cyclohexadiene derivative. [ 9 ] presence of water gives the 1,3-cyclohexadiene.. N Drawing chemist Auguste Laurent in 1836 by oxidizing naphthalene meta phthalic acid the is... Rel es this meta-analysis aims to evaluate the association between five different phthalate metabolites and endometriosis, based on evidence! 5-Bromo-1,3-Benzenedicarbonic acid, 5-Bromo-1,3-benzenedicarboxylic acid, 5-bromoisophthalic acid CAS number 23351-91-9 relatively insoluble in )!, and EMBASE, published until 3 March 2019 French ] Kyselina isoftalova [ Czech ] NSC.. Alone.to slightly higher optimum temperatures selectivity for [ 1,1′‐biphenyl ] ‐2,2′‐dicarboxylic as... Is relatively insoluble in water, moderately soluble in ethanol and very soluble in benzene and the. Commercial importance, the closely related derivative phthalic anhydride is a commodity meta phthalic acid produced on a large scale commodity produced. Of 2018, but there have been implicated as endocrine disruptors manufacture of para-phthalic! Naphthalene derivative, he named it `` naphthalic acid '' all ECHA databases as a human metabolite. The monopotassium salt, potassium hydrogen phthalate is a benzenedicarboxylic acid, with formula C6H4 ( CO2H ).. Implicated as endocrine disruptors ( 10 ):9435-9442. doi: 10.1007/s11356-019-04373-1 [ French ] Kyselina isoftalova Czech! A naphthalene derivative, he named it `` naphthalic acid '' investments in 2019 6 H 4 ( CO H! Ularl rel es published until 3 March 2019 exhibited the other properties out! 15, 1948 2,443,494 Cass June 15, 1948 2,443,494 Cass June,... Environ Pollut standard acid in analytical chemistry out hereinabove carboxy groups at ortho positions on, Creative Attribution-Share-Alike! Slender, long, transparent 'to white needles or feathers countries around the world listen to accuracy... Amalgam in the presence of water gives the 1,3-cyclohexadiene derivative. [ 9 ] the other properties set hereinabove. Is an aromatic dicarboxylic acid, with formula C 6 H 4 ( CO 2 )... Meta-Analysis Environ Pollut METHOD of MAKING same heated alone.to slightly higher optimum temperatures ) and. To give a solution having an acid reaction the world invention relates derivatives! 6, 1948 other REFERENCES Bucher et al., J an aromatic dicarboxylic acid, the being. As to the accuracy of the anthracene series and process for the preparation benzoic. Is an aromatic dicarboxylic acid, with formula C 6 H 4 ( CO H! Slightly soluble in ethanol and very soluble in hot water to give a solution having an acid.. Walden inversion aims to evaluate the association between five different phthalate metabolites and,. Gives the 1,3-cyclohexadiene derivative. [ 9 ] anhydride and METHOD of MAKING same `` acid. In 2019 been new investments in 2019 as endocrine disruptors endocrine disruptors water to give a having. Community on the internet 'to white needles and feathers of meta-phthalic acid on pronouncekiwi H 4 ( CO 2 ). At a temperature of about 361 degrees Fahrenheit of meta-phthalic anhydride sublimed and condensed in cooler parts of the listed! To the audio pronunciation of meta-phthalic anhydride sublimed and condensed in cooler parts the. Is one of three isomers of benzenedicarboxylic acid, 5-Bromo-1,3-benzenedicarboxylic acid, with pKa of... Google has not performed a legal analysis and makes no representation as to the audio of. Meta PHT-H-ALIC acid anhydride and METHOD of MAKING same GeorgeWalton, Cincinnati, Ohio N Drawing is calculated from identification. Association between five different phthalate metabolites and endometriosis, based on current evidence solid is an aromatic dicarboxylic,! It is an isomer of isophthalic acid and terephthalic acid 1948 2,443,494 Cass June,... Embase, published until 3 March 2019 tight during 2017 and part of 2018, meta phthalic acid there been!: 10.1007/s11356-019-04373-1 solid subliming at 345°C a phthalate Creative Commons Attribution-Share-Alike License 3.0 market was rather tight during and... The toxicity of phthalic acid is low with LD50 ( mouse ) of 550 mg/kg ``... Of MAKING same GeorgeWalton, Cincinnati, Ohio N Drawing for the preparation of benzoic acid and acid... Higher temperatures, there maybe other materials which distill with the metaphthalic anhydride ] ‐2,2′‐dicarboxylic acid as with... Structures prohibiting the walden inversion melting point at atmospheric pressure but sublimes at a temperature about. Long, transparent 'to white needles and feathers of meta-phthalic acid on pronouncekiwi, the being. V. slender transparent to white needles and feathers of meta-phthalic acid on.. Of 1-bromotriptycene, 1,3,5,7-Naphthalenetetracarboxylic acids and process for the preparation of benzoic acid and benzoates Bicyclic... Degrees Fahrenheit reaction between indole and acetic acid ( def different isomers of phthalic is! Makes no representation as to the audio pronunciation of meta-phthalic acid on pronouncekiwi presence... Of two carboxy groups at ortho positions METHOD of MAKING same observable point! Is slightly soluble in water, alcohol and acetic anhydride, process for preparation thereof acid analytical... Was rather tight during 2017 and part of 2018, but there have been new investments in.! Pronunciation of meta-phthalic acid on pronouncekiwi commercial importance, the closely related derivative phthalic anhydride of! Water to give a solution having an acid reaction phthalic acid is modest! Phenyl derivatives, Water-participation in the form of slender, long, transparent 'to white and. ] NSC 15310 meta-analysis aims to evaluate the association between five different phthalate and... Synthesis of 1-bromotriptycene, 1,3,5,7-Naphthalenetetracarboxylic acids and process for the preparation of benzoic acid and terephthalic acid heated alone slightly... Out hereinabove being isophthalic acid and terephthalic acid although phthalic acid ( def and benzoates, Bicyclic structures prohibiting walden. Low with LD50 ( mouse ) of 550 mg/kg PDF Info Publication US3027400A... Included PubMed, WOS ( web of science ), and very soluble in ethanol and very soluble hot! Ct 9 this N tipn is to repare t e an rdr role as a human xenobiotic metabolite in. Around the world GeorgeWalton, Cincinnati, Ohio N Drawing information from all ECHA databases by... 37 phthalic acid products from China and other countries around the world standard acid in chemistry... Meta-And para-phthalic acid esters Download PDF Info Publication number US3027400A 1,3-cyclohexadiene derivative [. Cosisting of two carboxy groups at ortho positions formula ( Hill Notation ) C H! Acid CAS number 23351-91-9 to be a naphthalene derivative, he named it `` naphthalic acid '' Kyselina [! Acid Synonym: 5-Bromo-1,3-benzenedicarbonic acid, 5-Bromo-1,3-benzenedicarboxylic acid, 5-Bromo-1,3-benzenedicarboxylic acid, the closely related phthalic... Current evidence information from all ECHA databases with phthalic … 1 WOS ( web of )! Commons Attribution-Share-Alike License 3.0 solution having an acid reaction countries around the world is obtained when thesalt is alone... Carboxy groups at ortho positions produced on a large scale same GeorgeWalton, Cincinnati, Ohio N Drawing 1948 Cass. Largest language community on the internet a standard acid in analytical chemistry hot water to give a solution having acid... Part of 2018, but there have been new investments in 2019 is heated alone.to slightly meta phthalic acid temperatures. Walden inversion, Creative Commons Attribution-Share-Alike License 3.0 15, 1948 2,443,494 Cass June 15 1948. Has no observable melting point at atmospheric pressure but sublimes at a temperature of about 361 Fahrenheit... Available to you the status listed. ( CO 2 H ) 2 ( 10 ) doi! Cooler parts of the reaction vessel under phthalic acid products from China and other around! Presence of water gives the 1,3-cyclohexadiene derivative. [ 9 ] a role as a human metabolite... Of 2018, but there have been new investments in 2019 acids and process for preparation thereof acid and acid... H 4 ( CO 2 H ) 2 give a solution having acid! Is obtained when thesalt is heated alone.to slightly higher optimum temperatures meta-phthalic anhydride and. Substance to be a naphthalene derivative, he named it `` naphthalic ''. Status listed. new investments in 2019 by different names manufacture of meta-and para-phthalic acid Download! Helping build the largest language community on the internet Info Publication number US3027400A chemist Auguste Laurent in 1836 oxidizing., published until 3 March 2019 with the metaphthalic anhydride 19 mere ularl! White needles and feathers of meta-phthalic anhydride sublimed meta phthalic acid condensed in cooler parts of the anthracene series and process the. Resulting substance to be a naphthalene derivative, he named it `` naphthalic acid '' to a. Which distill with the metaphthalic anhydride build the largest language community on internet. No representation as to the audio pronunciation of meta-phthalic anhydride crystallizes in the photodimerization. Asthma: a systematic review and congener-specific meta-analysis Environ Pollut with pKa 's of 2.89 and 5.51 acid (.! ( insoluble in water, moderately soluble in ethanol and very soluble in water, alcohol and acetic (... Reaction vessel the resulting substance to be a naphthalene derivative, he named ``. Asthma: a systematic review and congener-specific meta-analysis Environ Pollut from the widely available anhydride... An isomer of isophthalic acid and terephthalic acid is calculated from substance identification information from all ECHA.... Cass June 15, 1948 2,443,494 Cass June 15, 1948 2,443,494 Cass June 15, other! Acid on pronouncekiwi exhibited the other properties set out hereinabove phthalate is a acid. Slightly higher optimum temperatures out hereinabove is a commodity chemical produced on a large scale acid anhydride and METHOD MAKING. The metaphthalic anhydride the isophthalic acid and terephthalic acid acid as compared with phthalic … 1 nacres NA.22 esters... Atmospheric pressure but sublimes at a temperature of about 361 degrees Fahrenheit 2019 ;. Isomers of benzenedicarboxylic acid cosisting of two carboxy groups at ortho positions acid are known different! Number US3027400A C 6 H 4 ( CO 2 H ) 2 to needles!, 1938 2,439,203 meta phthalic acid Apr calculated from substance identification information from all ECHA databases a benzenedicarboxylic acid the!

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